Method of laundering clothes and detergent composition therefor

专利摘要:
The main washing | cleaning action is the cleaning composition obtained with an alkaline inorganic salt, and also wash | cleans using the cleaning composition containing at least an antifouling agent. Provided is a laundry method for medical treatment using a cleaning agent whose main cleaning action is obtained by inorganic salts, which has a cleaning power equivalent to or greater than that of a synthetic detergent containing a surfactant as a main component, and which is also excellent in recontamination prevention performance, and a cleaning composition for the same. do.
公开号:KR20030070056A
申请号:KR10-2003-7007616
申请日:2001-12-05
公开日:2003-08-27
发明作者:아라이가즈요시；세오도모키
申请人:미즈 가부시키가이샤；
IPC主号:

专利说明:

Method of laundering clothes and detergent composition therefor}
[2] Synthetic detergents have received overwhelming support in the medical care because of their superior cleaning power and ease of use. However, synthetic detergents do not only benefit consumers. For example, synthetic detergents have undergone frequent improvements through environmental burdens caused by alkylbenzenesulfonic acid soda or phosphate builders formulated therein, but in recent years, synthetic detergents have become a potential environmental hormone. Issues such as impact are also beginning to arise. Moreover, it is true that surfactant contained in a synthetic detergent remains in medical quantity no matter how much rinsing is performed, and the probability that such surfactant will affect a human body through skin cannot be denied. In addition, a large amount of water discarded upon rinsing over a large number of times performed for the purpose of removing the surfactant cannot be used as a valuable resource.
[3] Soaps, which have been used since ancient times and are considered to be good in safety, cannot be largely made even by those who question the safety of synthetic detergents due to their ease of use. In addition, even though soaps are more biodegradable than synthetic detergents, the amount of the soaps used does not necessarily lead to a reduction in environmental burden.
[4] Excellent cleaning performance by surfactants is widely recognized, but considering the effects on living organisms and the environment, in the case of a detergent that is substantially free of surfactants or has significantly reduced the amount of surfactant used, washing performance and ease of use The emergence of new detergents equivalent to this synthetic detergent is expected.
[5] Substantially free of surfactants, medical cleaning agents containing alkaline inorganic salts as a main component are also previously used for washing soda (sodium carbonate hydrate), and recently disclosed in Japanese Patent Laid-Open No. 9-87678. As described above, in addition to sodium bicarbonate (heavy bath) in order to enhance the cleaning power, a compound containing an enzyme has been proposed.
[6] However, these conventionally known cleaning agents having alkaline inorganic salts as their main components are inferior to laundry soaps and synthetic detergents in terms of washing performance and ease of use, and are particularly inferior to synthetic detergents.
[7] INDUSTRIAL APPLICABILITY The present invention is a detergent composition which substantially does not use a surfactant that is in doubt from the viewpoint of safety to the human body or a reduced environmental burden, or significantly reduces the amount of the surfactant used. It is an object of the present invention to provide a cleaning composition having a washing performance equal to or higher than that of one laundry soap or a synthetic detergent, ease of use, and a cleaning method using the same.
[1] The present invention relates to a laundry method of medical care for washing alkaline inorganic salts as a main component of a cleaning action, and a detergent composition therefor.
[139] BRIEF DESCRIPTION OF THE DRAWINGS It is a figure which shows the change of the washing | cleaning rate at the time of changing the density | concentration parameter of the washing | cleaning liquid concerning this invention.
[140] It is a figure which shows the evaluation result of recontamination prevention performance by Pluronic.
[8] In view of the above object, the present inventors have focused on the fact that the main cleaning action is obtained by using an alkaline inorganic salt, that is, an alkaline inorganic salt is the main component of the washing action, and as a result, the present inventors have studied a conventional cleaning agent having an alkaline inorganic salt as a main component. It was estimated that the composition of the alkaline inorganic salt was inadequate, and that, as a larger factor, little recontamination prevention performance hindered the specification of the practical washing performance.
[9] In other words, the washing effect (sometimes referred to as washing performance) in medical washing is a re-contamination in which cleaning power that separates contamination from medical care and contamination dispersed in the cleaning liquid do not reattach to medical care and contaminate medical care. Both of the prevention performances are obtained in cooperation. If the recontamination prevention performance is insufficient, the purpose of the washing is not sufficiently achieved due to recontamination when washing laundry that is heavily polluted, and when washing lightly contaminated laundry, contamination is accumulated through repeated washings. It leads to graying, which is also forced to say that the washing effect is insufficient.
[10] The present inventors focus on these problems in the alkaline inorganic salt cleaning agent, and mainly consider the composition of the alkaline inorganic salt cleaning main component and the anti-contamination agent, and also consider some additives to substantially use the surfactant. It is a detergent composition which is free of the present invention, and provides a cleaning composition comprising a alkaline inorganic salt as a main component having a washing performance and ease of use equivalent to or more than that of a laundry soap or a synthetic detergent based on a conventional surfactant and a cleaning method using the same. It has been found that it can be done and the present invention has been completed.
[11] (1) alkaline inorganic salt cleaner
[12] According to the present invention, there is provided a medical cleaning composition comprising an inorganic salt forming an alkaline buffer system as a main cleaning action component and further containing at least a recontamination prevention component.
[13] 1-1) Composition of alkaline inorganic salts:
[14] The alkaline inorganic salt in the present invention contains, as a main component, a pH buffering salt mainly responsible for the pH buffering action and an alkali functional salt mainly responsible for the alkaline action. When the detergent composition of the present invention is dissolved in water for washing, the pH indicated by the standard concentration of the cleaning liquid is in a weakly alkaline range of 9 to 11, without damaging the fibers and ensuring sufficient stability to the user. Washing is possible.
[15] In general, in medical washing, high cleaning power is required within a weakly alkaline range of pH 9-11. However, since the pH of the alkaline agent depends on the concentration, in order to converge the pH within this weakly alkaline range, the use concentration must be at a low level, and as a result, sufficient cleaning power could not be obtained. The data shown in Table 1 were obtained for pH, concentration and detergency.
[16] Table 1
[17]
[18] According to Table 1, in the case of alkali salts alone, since it does not become a sufficient density | concentration in the range of pH 10 or less, it has the washing power about the same as the sodium hydrogencarbonate aqueous solution of pH 8.3 or so. On the other hand, in the case of a system in which the sodium bicarbonate is mixed without the alkali salt alone system, it can be seen that the cleaning power equivalent to that in the case where the pH is high can be obtained by increasing the concentration even at a relatively low pH in the region of pH 9 or more.
[19] Therefore, coexistence of pH buffering salts such as sodium bicarbonate can form a buffer system and sufficiently increase the concentration of the alkaline agent while suppressing the promotion of alkalizing due to the increase of the concentration of the alkaline functional salts.
[20] In the aqueous solution of carbonate or bicarbonate, the ratio of -divalent carbonate ions and -monovalent bicarbonate ions depends on the pH of the aqueous solution, and at pH 10.3 the ratio is approximately 1: 1. In the high pH region, carbonate ions increase, and in the low pH region, bicarbonate ions turn into carbon dioxide gas. In addition, the higher the ratio of bicarbonate ions, the stronger the buffering effect, and even if the concentration is changed, the pH hardly changes. Therefore, by mixing carbonates (carbonate ions) and bicarbonates (bicarbonate ions), the pH of any weakly alkaline region can be obtained, and the concentration of the alkali agent can be increased, and the cleaning liquid with a small pH change due to the alkali agent concentration can be obtained (Table 2). Reference).
[21] Table 2
[22]
[23] In addition, even if an acidic contamination, for example, is mixed in the cleaning liquid, the pH buffering salt acts to suppress the acidification of the cleaning liquid. As a result, the cleaning liquid can be converged and maintained in a weakly alkaline range suitable for washing. You can also.
[24] Examples of the pH buffering salt in the present invention include alkali bicarbonate metal salts, alkali borate metal salts, alkali metal phosphate salts, and the like, and organic acid salts such as alkali metal oxalate salts and alkali metal phthalate salts may also be used as auxiliary. Moreover, with alkali functional salt in this invention, an alkali metal carbonate salt, the alkali metal silicate salt, etc. are mentioned, for example.
[25] In the present invention, the inorganic salt preferably contains an alkali metal bicarbonate salt, an alkali metal carbonate salt and / or an alkali metal silicate salt as main components. As described above, the main role of the alkali metal bicarbonate salt is pH buffering action, and the main role of the alkali metal carbonate salt and alkali metal silicate salt is promotion of the alkalinization of the liquid represented by the washing liquid.
[26] On the other hand, the composition of the alkaline inorganic salt of the present invention basically contains an alkali metal bicarbonate salt in order to take advantage of its pH buffering action. Since it becomes a system which has some buffering effect, it is included in the category of the alkaline inorganic salt composition of this invention.
[27] The alkali metal carbonate also has a good softening-promoting action as described later. On the other hand, the alkali metal silicate salt has an improvement in the prevention of re-contamination and rust prevention of the metal surface of the washing machine, It also has a fixing effect.
[28] Alkali silicate metal salts, in particular sodium metasilicate, generate colloids in the cleaning liquid and have the action of dispersing the inorganic contaminating particles into the cleaning liquid, thereby preventing adsorption of the contaminating particles to the fiber, that is, recontamination. In addition, in the cleaning composition of this invention, the alkali silicate metal salt, especially sodium metasilicate (pentahydrate), can be substituted with sodium carbonate in arbitrary ratios, without impairing cleaning power.
[29] On the other hand, in order to give sufficient recontamination prevention performance, it is preferable to set the density | concentration of the alkali metal silicate salt so that it may become 0.001 mol / liter or more in a washing | cleaning liquid.
[30] In this invention, it is preferable that the compounding ratio in the cleaning composition total amount of the total amount of the said inorganic salt is 90 weight% or more. Further, the inorganic salt compounding ratio is more preferably 91% by weight or more, provided that the recontamination preventing material described below is present so that the recontamination preventing ability reaches a level equivalent to that of conventional laundry soap or synthetic detergent. In the same manner, the inorganic salt blending ratio is 92% by weight or more, the inorganic salt blending ratio is 93% by weight or more, the inorganic salt blending ratio is 94% by weight or more, the inorganic salt blending ratio is 95% by weight or more, the inorganic salt blending ratio is 96% by weight or more, and the inorganic salt. In order of 97 weight% or more of compounding ratios, 98 weight% or more of inorganic salts, and 99 weight% or more of inorganic salts, the more compounding quantity of the inorganic salt in a cleaning composition is more preferable. It is because the effect of the improvement of the washing power by a main component is acquired.
[31] In this invention, it is more preferable that the composition ratio of the number-of-moles of the alkali metal bicarbonate salt and the number-of-moles of the alkali metal carbonate salt is 1: 7-1: 0.2. In the present invention, in order to avoid any damage such as fiber damage, skin damage or necessity of drainage treatment caused by liquid alkali of the cleaning liquid, by containing an alkali metal bicarbonate salt which is a pH buffering salt as an essential component, Although the pH of the washing | cleaning liquid at the time of washing | cleaning (for example, 1 g / L (0.1 weight%) density | concentration) is converged to 9-11 which is a weak alkaline range, the number-of-moles containing the alkali metal bicarbonate salt which can form such a pH buffer system, The composition ratio of the number-of-moles containing an alkali metal carbonate salt corresponds to 1: 7-1: 0.2.
[32] In the case of the combination of an alkali metal bicarbonate salt and an alkali metal silicate salt, the content mole number ratio of 1: 1.2 to 1: 0.1 is likewise preferable.
[33] In addition, as an inorganic salt which forms an alkaline buffer system as said main washing | cleaning action component, when using three types of alkali bicarbonate metal salts, alkali carbonate metal salts, and alkali silicate metal salts, alkali metal silicate salts, for example, sodium metasilicate In consideration of this recontamination prevention performance exhibited, it is preferable to set the compounding quantity of the alkali metal silicate salt so that it may become 20 to 90 weight% of a cleaning agent total weight, Preferably it is 30 to 70 weight%.
[34] The total amount of the inorganic salt, the alkali bicarbonate metal salt and the alkali carbonate metal salt and / or alkali silicate metal salt may be blended according to the type of the laundry to which the cleaning composition is targeted, the hardness of water in the region to be sold, the washing temperature and the washing machine. A suitable ratio can be selected according to washing conditions, such as a type | formula. For example, in the case of medical washing that is susceptible to damage, the formulation should have a low alkalinity, that is, a high proportion of alkali metal bicarbonate salts. It is preferable to mix | blend a large amount of alkali metal salt in a high ratio.
[35] When using sodium salt as an alkali bicarbonate metal salt and an alkali carbonate metal salt in the combination of the said inorganic salt, sodium sesquicarbonate which is an equimolar mixture of these substances can be substituted in the said composition ratio.
[36] 1-2) pH and inorganic salt concentration of cleaning solution:
[37] PH of the washing | cleaning liquid can be adjusted with the compounding ratio of the alkali metal bicarbonate salt, for example sodium bicarbonate, in a main component mixture. The relationship between pH and detergency was investigated with a washing solution in which the mixture of sodium carbonate and sodium bicarbonate was dissolved in tap water. The results are shown in Table 3.
[38] Table 3
[39]
[40] From Table 3, there is no significant difference up to about pH 9.3 compared to that of tap water alone, but a significant increase in the cleaning rate is seen from the vicinity exceeding pH 9.5. On the higher pH side, the cleaning rate still tends to increase in the range of weak alkaline, but the upper limit of the preferred pH is determined in view of the compatibility with the added enzyme and the like.
[41] Therefore, from the viewpoint of the cleaning power, the pH of the cleaning liquid when the cleaning composition of the present invention is dissolved in water at a standard use concentration, for example, 1 g / L (0.1 wt% concentration), is preferably 9.5 or more.
[42] Next, Table 4 and FIG. 1 show the relationship between the inorganic salt concentration and the cleaning power in the cleaning liquid of the present invention.
[43] Table 4
[44]
[45] The higher the inorganic salt concentration, the more the washing rate tends to increase, but almost no increase is seen from some places. Moreover, as a characteristic of this detergent, there exist two "flat parts" in which the rise change of the cleaning rate becomes substantially flat. There is a relatively large difference between the cleaning rates of the first flat part and the second flat part, and the higher the concentration, the higher the cleaning rate. However, the concentration is roughly twice or more, and the increase in the amount of use per one is large.
[46] There are several aspects of setting the standard concentration of the inorganic salt in the cleaning liquid, such as performance, environmental response, and cost. However, it is assumed that it is appropriate to set the minimum concentration that has no practical problem in terms of cleaning power. In other words, under the condition of a low hardness product such as Japan and low temperature washing, in the case of the powder cleaning agent of the present invention, the use concentration of about 30 to 60 g / 30 L wash water, in other words, 1 to 2 g / liter (hereinafter, "L"). (May be omitted).
[47] On the other hand, the weakly alkaline inorganic salt cleaning liquid of the present invention is disclosed in Japanese Patent Application Laid-Open No. 11-837414, or Japanese Patent Application Laid-Open No. 2000-820549, to which the applicant of the present application has been filed and disclosed first, and whose disclosure is incorporated in the specification by reference. Also disclosed is an aqueous solution of an alkaline inorganic salt having a pH of 9 to 11 containing carbonate ions and bicarbonate ions produced by electrolyzing an aqueous solution of sodium bicarbonate (sodium bicarbonate or sodium bicarbonate).
[48] 1-3): Softening of Washing Water:
[49] Polyvalent cations (hard components), including calcium ions and magnesium ions, which are contained in tap water and well water, attract the protons in a form that plays a role as a medium for both the negatively charged contamination and the fibers in the cleaning liquid. It becomes one of the causes of adhering pollution to the. In the inorganic salt cleaning agent of the present invention, these polyvalent cations are associated with carbonate ions contained in the cleaning liquid, and insoluble carbonates are generated in the cleaning liquid to reduce the deterrent to the cleaning power derived from the polyvalent cations. Although carbonate ions are consumed through the production of insoluble carbonates, the concentration of alkali metal carbonates is much higher than that of polyvalent cations, so that they correspond to the hardness component in the smallest amount of builder needed to function the surfactant. When the synthetic detergent of the thinking method is compared with the cleaning agent of the present invention, the cleaning agent of the present invention is less affected by the hardness of the washing water. However, in a region where the amount of hardness components of the washing water is extremely large, it is necessary to secure the cleaning power by sufficiently increasing the amount of carbonate ions of the cleaning agent of the present invention, that is, the concentration of the cleaning agent.
[50] The invalidation of the hardness component, that is, the progress of water softening, is changed as follows depending on the situation and conditions in which the cleaning liquid in which the cleaning agent of the present invention is dissolved is placed. This is shown in Table 5.
[51] Table 5
[52]
[53] According to Table 5, when it is left as it is, reaction advances slowly and it takes about 3 hours to fall to the low hardness which is effective for improving cleaning power. However, when a physical force such as stirring is added after dissolution dilution, the reaction is accelerated and lowered to the equivalent level in about 30 minutes. Furthermore, when a cloth is put and stirred, it accelerates to 5 to 10 minutes. This property is convenient for washing. Since these reaction promoting elements are the same as the physical action imparted in normal washing by the washing machine, the softening can be promoted without any special operation.
[54] Here, the mechanical force such as stirring is effective in increasing the contact chance of polyvalent cations and carbonate ions in the cleaning liquid, and the effect of increasing molecular motion by ultrasonic vibration or heating is also similar. In addition, it is estimated that the fine calcium carbonate adhering to the surface of the cloth acts catalytically to promote the reaction in the case of medical treatment such as cloth.
[55] If the hardness of the wash water is higher, it is considered that the softening time is longer in proportion to the hardness. However, in practice, the higher the initial hardness, the greater the decrease in hardness. Therefore, in the case of stirring with cloth, approximately 15 It decreases to the equivalent hardness at the time of minute passing.
[56] On the other hand, in actual washing, the hardness component in the cleaning liquid is not only contained in the washing water, but also the total amount of the substance attached to the laundry to be rinsed, included in the sweat from the human body, included in the attached contaminants, and the like. Since they elute slowly, the hardness of the cleaning liquid does not become a fixed value or less, and the hardness in the cleaning liquid may increase on the contrary in the case where the washing time is extended.
[57] Here, the relationship between pH and the softening effect when the cleaning liquid concentration is constant (0.8 g / L) is examined.
[58] First, pH was changed by changing the mixing ratio of sodium carbonate and sodium bicarbonate as a main component, and the change of the hardness fall time at this time was investigated. The results are shown in Table 6.
[59] Table 6
[60]
[61] According to Table 6, it turns out that there is a big change between pH 9.3 and 9.8, and the higher pH leads to shortening of the hardness fall time, but it becomes a limit in the place over pH 9.8. From this result, it turns out that it is good to set pH to about 9.5 or more in order to reduce hardness efficiently.
[62] Therefore, in addition to the viewpoint of the cleaning power, the pH of the cleaning liquid is preferably 9.5 or more from the viewpoint of the softening rate.
[63] Thus, in this detergent, since the main component has an effect which invalidates this by reacting with the hardness component which becomes a factor which inhibits washing power, it is practical without adding a water softening agent, such as an organic chelating agent and water-insoluble zeolite normally used as a synthetic detergent component. A softening effect can be obtained. However, in order to further improve the performance by adding a softening agent such as a chelating agent to the present cleaning agent, softening is promoted in the same manner as described above, and after a certain time, a small amount of softening agent such as a chelating agent is added halfway. The softening agent of can promote the softening more effectively. However, in the case where the reaction time is relatively long like zeolite, it is difficult to exert the same effect within a predetermined washing time of about 8 to 12 minutes under the premise of intermediate addition. As other softeners, fatty acid soaps can be preferably used in view of degradability and safety. In this case, since the purpose is softening, it is not necessary to add an amount sufficient to exert the cleaning power. Moreover, since an alkaline component is contained in a washing | cleaning liquid, the fatty acid, such as oleic acid, can be added instead of a fatty acid salt, and the method of producing metal soap in a washing | cleaning liquid can also be used.
[64] (2) anti-contamination ingredients
[65] In synthetic detergents, surfactants have not only detergency but also sufficient dispersibility (recontamination resistance) by themselves, but in order to further improve recontamination prevention performance, a small amount of recontamination inhibitor is often added. In particular, the dispersibility of solid particle contamination is related to the re-adhesiveness (re-contamination) to the cloth of contamination which has fallen off, and many surfactants have the ability to adsorb to and disperse solid particle contamination.
[66] However, in the case of the inorganic salt of the present invention, since the action of dispersing such solid particles can hardly be expected, in the actual washing system in which oil contamination or hydrophobic contamination other than solid particle contamination exists and is complexed as a single washing liquid. In addition, adhesion to medical care or recontamination, as well as attachment to the washing tank is inevitable.
[67] In general, various mechanisms for preventing recontamination are estimated, such as solubilization and dispersion of contamination, electrical repulsion of fibers and contamination, and the like. The present inventors have diligently studied the inorganic salt cleaning agent of the present invention for the purpose of imparting recontamination prevention performance, and as a result, recontamination occurs when the surface tension of the cleaning liquid is high, and a slight decrease in surface tension ( Up to about 58 dyn / cm) reveals that recontamination can be significantly prevented. However, it was mainly found that recontamination prevention to hydrophilic fibers is required, and in order to obtain more sufficient recontamination prevention performance in the present invention, it was found that the adsorption capacity to hydrophobic fibers or nonpolar contamination, that is, the ability to disperse them is also required. In addition, in the cleaning liquid system of the present invention having the inorganic salt as the main cleaning action component, since the original ion content is large, the addition of the anti-contamination prevention component that is expected to be electrostatic repulsive force is not effective, and the problem is that electrostatic It was found that it is a nonpolar solid contaminated particle or a mixture of solid contaminated particles and hydrophobic contaminants that do not cause adsorption, and also prevents recontamination of hydrophobic fibers.
[68] Therefore, in order to obtain the recontamination prevention performance required in the present invention, (1) the performance of reducing the surface tension of the cleaning liquid below the predetermined surface tension (called surface tension reducing ability), and (2) hydrophobic fibers It is preferable to provide both of the performance (henceforth hydrophobic recontamination prevention ability) which adsorb | sucks to nonpolar pollution and disperse | distributes contamination.
[69] The "predetermined" surface tension lowering ability herein refers to the surface tension of the same cleaning liquid with respect to the cleaning liquid obtained by dissolving the inorganic salt cleaning agent of the present invention in water at an actual use concentration of 1 g / L (0.1 wt. Refers to the ability to lower the ratio to 58 dyn / cm or less. With respect to the surface tension-lowering ability acting on the main cleaning liquid, a "damp test" was carried out for the purpose of confirming a limit necessary for providing practical recontamination prevention ability. In this ink test, the behavior of the ink when a small amount of ink is added to each of the cleaning liquids of the present invention at each concentration is observed and spreads to the surface to contaminate the inner wall of the washing tank (no surface tension lowering action), or the surface of the cleaning liquid. It is determined whether or not the surface tension lowering action under each concentration of the cleaning liquid of the present invention is determined by dropping or dispersing in the cleaning liquid vertically (with a surface tension lowering action). The results are shown in Table 7.
[70] Table 7
[71]
[72] Also from the results in Table 7, the surface tension of the cleaning liquid of the present invention can be reduced to 58 dyn / cm or less, which can support that it is possible to exhibit a constant recontamination prevention ability.
[73] On the other hand, the recontamination prevention component used in the present invention not only falls into the category of the water-soluble high molecular substance usually used as the recontamination inhibitor, but also is blended in the cleaning liquid system of the present invention in an amount of less than or equal to the critical micelle concentration, so as to be prescribed. It also includes using a surfactant having a surface tension lowering action.
[74] Next, in order to search the range of the anti-contamination component that can be used in the present invention, the amount of the present invention is about 1/10 or less of the standard surfactant concentration (anionic system) in the conventional synthetic detergent. Various cleaning agents (sometimes referred to as dispersants) are the same cleaning solution so as to have a concentration of about 0.017 g / L in the cleaning liquid (corresponding to the component concentration when 0.5 g of recontamination preventing component is dissolved in 30 L of washing water). It added in the middle and evaluated the recontamination prevention performance at this time. Meanwhile, the composition of the cleaning composition of the present invention is 28.6 g of inorganic salt main component + 0.5 g of each recontamination preventing substance, and the composition of the inorganic salt main component is 10 g of sodium carbonate + 7.8 g of sodium bicarbonate + sodium metasilicate 5 10.8 g of hydrate. Two types of cotton and polyester fiber were used as test | inspection medicine, the fixed amount of ink was dripped as contamination, and the white-white difference before and after washing when wash | cleaned in the test | cleaning liquid was compared. In addition, this recontamination prevention performance evaluation test is doing on the conditions according to the recontamination test conditions mentioned later. The results are shown in Tables 8 to 10.
[75] Table 8
[76]
[77] Table 9
[78]
[79] Table 10
[80]
[81] As a result, the various recontamination preventing substances have (a) the surface tension lowering ability and the hydrophobic recontamination preventing ability, the substance alone and the low concentration, sufficient recontamination preventing effect, (b) the surface tension lowering ability or Although it has only one of the said hydrophobic recontamination prevention ability, it cannot be used alone as a recontamination prevention component of this invention, but it is combined with each other and supplemented with them, or in combination with the dispersing agent of said (a), It is possible to obtain the effect of preventing recontamination, and (c) the effect is not obtained unless the concentration is equivalent to that of the conventional synthetic detergent, or the recontamination prevention effect is not obtained in the inorganic salt cleaning system. Separated.
[82] The dispersant which can be used as the recontamination prevention component of this invention is a group of (b) which can be used by combining with (a) group which can also be used alone, and others as mentioned above.
[83] Examples of the (a) group include methyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose, partially saponified polyvinyl alcohol, polypropylene glycol, and polyoxyethylene polyoxypropylene block copolymers. And nonionic water-soluble high molecular materials or nonionic surfactants.
[84] Meanwhile, as belonging to the group (b), water-soluble high molecular substances such as sodium polyacrylate, polyethylene glycol, hydroxyethyl cellulose, carboxymethyl cellulose, polyvinylpyrrolidone, polyoxyethylene sorbitan monooleate, polyoxyethylene And nonionic or bipolar surfactants such as sorbitan monolaurate, polyglycerin fatty acid ester, ethylene glycol and laurylamide propyl acetate betaine.
[85] It can be said that it belongs to the group (a) in a small amount to lower the surface tension of the cleaning liquid to about 58 dyn / cm or less, and also has good adsorption and dispersibility to hydrophobic fibers and nonpolar contamination. On the other hand, the good hydrophobic recontamination prevention ability is also good in the adsorptivity and dispersibility with respect to hydrophilic fiber and polar contamination.
[86] The group belonging to the group (b) includes a nonionic or bipolar dispersant having a surface tension lowering ability but weak dispersibility, and an anionic dispersing agent having a dispersing ability but no surface tension lowering ability, and is relatively effective in hydrophilic fiber and polar contamination. However, on the premise that they have little effect on hydrophobic fibers or nonpolar contamination, and obtain recontamination prevention performance in small amounts for both cotton and chemical fibers (polyester), those belonging to group (b) alone are sufficient. Obtaining anti-contamination performance tends to be difficult.
[87] Although the recontamination prevention performance of the thing belonging to (a) group becomes good with the increase of concentration, it is preferable to use in low concentration range as much as possible practically from a viewpoint of environmental burden reduction etc. On the other hand, no matter how high the concentration of these recontamination preventing materials, the lowering of the surface tension is the limit, and the cleaning power has almost no influence by the concentration.
[88] They are shown by the example tested on polyvinyl alcohol (refer Table 11).
[89] Table 11
[90]
[91] Moreover, the influence when the parameter of polymerization degree is changed about the recontamination prevention performance of partial saponification type polyvinyl alcohol is shown (refer Table 12).
[92] Table 12
[93]
[94] According to Table 12, favorable results are obtained until the molecular weight is about 1000 in partial saponification type polyvinyl alcohol (PVA).
[95] In addition, in order to see the influence of the hydrophobic group, a test was carried out on the pluronic which can change various molecular weight composition ratios of the hydrophilic polyoxyethylene and the hydrophobic polyoxypropylene in various ways to obtain the results of FIG. 2.
[96] From the evaluation result of recontamination prevention performance of FIG. 2, the magnitude | size (molecular weight) of hydrophobic group exceeded 3000, and shows favorable effect. Although the molecular weight (total molecular weight) of the whole increases in the right and top directions of the grid, even if the total molecular weight is the same, it is estimated that the size of the hydrophobic group is important because the small hydrophobic groups are almost ineffective. In the case where the hydrophobic groups are the same size, the smaller the proportion of the total molecular weight of the hydrophilic group is, the better the recontamination prevention ability with respect to the hydrophobic fibers. In other words, if the hydrophobic groups have the same size, it can be said that the smaller the total molecular weight is, the more favorable for the hydrophobic fibers.
[97] From the above findings, the water-soluble high molecular substance can be preferably used as the recontamination prevention component in the present invention, and two of the substances which can be more preferably used are generally nonionic and those having a large hydrophobic group. It is a substance that satisfies the conditions. Among these, a substance which can be used more preferably is a relatively low molecular weight substance having an average molecular weight of about 10 to 500,000, more preferably a substance of about thousands. Further, from the viewpoints of safety and biodegradability, cellulose, polyhydric alcohol, fatty acid and the like are preferable, and specifically, methyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose, and partially saponified poly Vinyl alcohol and the like are particularly preferred.
[98] In addition, there are hydrophilic fibers and hydrophobic fibers in medical treatment, and the recontamination prevention component is also compatible with such fibers, and in order to obtain sufficient recontamination prevention performance, the (a) group is used rather than the single use of the substance of the (a) group. Combinations of materials within or combinations of materials of (a) group and materials of group (b) are effective, and two or more suitable combinations of materials in group (a) of the former are most preferred.
[99] Table 13 shows the results of evaluation of the combination of various recontamination prevention components.
[100] Table 13
[101]
[102] From Table 13, a good combination of the re-contamination prevention material of group (a) showing a good result for cotton and a good result for polyester fiber, for each of the hydrophilic and hydrophobic fibers in small amounts It can be seen that the recontamination prevention effect can be exhibited in a good balance. Especially, especially favorable result was obtained by the combination of 1: 1 of partial saponification type polyvinyl alcohol and hydroxypropyl methylcellulose.
[103] In the cleaning composition of this invention, it is preferable that the total amount of a recontamination prevention component is 10 weight% or less of the total amount of cleaning composition.
[104] And on the condition that the recontamination prevention performance has reached the practical level, it is more preferable that the total amount of a recontamination prevention component is 9 weight% or less of the total amount of a cleaning composition, and similarly below 8 weight% or less of a total amount of a cleaning composition, and a cleaning agent 7 wt% or less of the total amount of the composition, 6 wt% or less of the total amount of the cleaning composition, 5 wt% or less of the total amount of the cleaning composition, 4 wt% or less of the total amount of the cleaning composition, 3 wt% or less of the total amount of the cleaning composition, and 2 weight of the total amount of the cleaning composition. In order of% or less and 1 weight% or less of the cleaning composition total amount, it is more preferable that the compounding quantity of the recontamination prevention component in a cleaning composition is small.
[105] In the present invention, the recontamination prevention component such as a water-soluble polymer is an organic substance having an important role, and the amount of such organic substance is as small as possible for the purpose of the present invention to reduce the environmental burden.
[106] Moreover, the recontamination prevention component density | concentration in the washing | cleaning liquid obtained by melt | dissolving the inorganic detergent composition of this invention with water so that it may become 1 g / L under normal use should be at least 0.007 g / L (0.0007 weight%, 30L wash water). Corresponding to the component concentration when 0.2 g of the recontamination prevention component is dissolved), preferably 0.01 g / L (0.001% by weight, to the component concentration when 0.3 g of the recontamination prevention component is dissolved in 30 L of washing water). Equivalent). Moreover, when the inorganic salt compounding ratio in the cleaning composition of this invention is 90 weight%, the upper limit of the compounding ratio in the same composition of a recontamination prevention component turns into 10 weight%, and this is the recontamination in the said washing liquid by this. 0.1 g / L (0.01 weight%, equivalent to the component concentration when 3 g of recontamination prevention components are melt | dissolved in 30 L of wash water) becomes an upper limit.
[107] As described above, the alkali metal silicate salt, which is one of the main inorganic salt cleaning components of the present invention, is not as effective as the antifouling substance belonging to the group (a), but may contribute to the improvement of the antifouling effect. By using together, the usage-amount of the organic type recontamination prevention substance which belongs to (a) group can be reduced.
[108] The improvement of the recontamination prevention performance when the silicate or the organic recontamination prevention material was added to the inorganic salt main component regarding the combination of bicarbonate and a carbonate was confirmed. Sodium metasilicate was replaced by the same weight ratio as sodium carbonate in the main component, and the recontamination prevention ability when the blending ratio was gradually increased was evaluated. On the other hand, the quantity of the organic type antifouling substance was made constant.
[109] Table 14
[110]
[111] From this result, sodium metasilicate (as pentahydrate) is preferably 30 to 70% by weight of the total amount of the detergent.
[112] By using the water-soluble silicate together with the anti-recontamination substance belonging to the group (a), the lower limit concentration of the organic re-contamination prevention component contained in the cleaning liquid is lowered to about 0.007 g / L (0.0007% by weight), which is very practical. Recontamination prevention effect can be obtained. This corresponds to the amount of organic matter used in 1/10 or less compared with the conventional synthetic detergent and the like.
[113] (3) additive
[114] The cleaning agent of the present invention further includes a substance contained as a commercial ingredient in synthetic detergents such as washing enzymes, oxygen bleaches, bactericides, flavoring agents, softeners, foaming agents, etc., if necessary, within a range not departing from the spirit of the present invention. You may also
[115] Of these additives, the most important is the enzyme for washing. The cleaning system of the present invention containing the alkaline inorganic salt main component and the anti-contamination prevention component is useful for removing contamination that is not yet sufficiently removable. Washing enzymes include proteolytic enzymes (proteases), lipolytic enzymes (lipases), cellulose enzymes (cellulase), starch degrading enzymes (amylase), and the like, among which proteases are particularly effective against daily contamination, and cellular The agent is effective in maintaining the whiteness of cotton fibers, removing solid particles, and the like when repeatedly washed.
[116] The amount of the enzyme is preferably about 0.3% to 3% by weight based on the total amount of the detergent composition.
[117] In addition, since the liquidity of this washing | cleaning agent is weakly alkaline, when examining the mix | blending of an enzyme, you must select the thing whose activity value does not fall in the pH range. On the contrary, it is preferable not to set the pH range in consideration of the washing power by alkali salts, but to set the pH range in consideration of sufficiently exhibiting the activity of the enzyme blended in the composition.
[118] On the other hand, in the formulation of the enzyme into the cleaning agent, particular attention is given to the stability of the enzyme activity in the cleaning liquid, and in particular, care must be taken in deactivation by the effective free oxygen contained in the washing water. Moreover, although the washing | cleaning agent of this invention makes carbonate one of the main components, since carbonate has the effect | action which promotes the oxidation reaction by effective free oxygen, special care is needed.
[119] Therefore, in the formulation in the cleaning agent, it is necessary to add the enzyme and the reducing agent at the same time. Although sulfite and thiosulfate are suitable as reducing agents, there is also a method of using ammonium salts such as ammonium sulfate salt as trapping active chlorine to prevent enzyme deactivation. These compounding quantities are about 0.3 to 3 weight% with respect to the cleaning agent total amount.
[120] Examples of the oxygen-based bleach include sodium percarbonate, sodium perborate, hydrogen peroxide and the like. Although the cleaning composition of this invention demonstrates the washing power equivalent to the synthetic detergent which used the conventional surfactant as a main component, even if an oxygen-based bleach is not used, the improvement of cleaning performance can be anticipated further by adding a bleach.
[121] The fungicides are formulated for the purpose of preventing the decay and mold of the cleaning composition containing organic matter other than the sterilization of the object to be cleaned, and can be appropriately selected from benzalkonium chloride, parabens and propylene glycol according to the purpose of use thereof. In consideration of the safety to the human body, it is preferable to add an extract extracted from the seeds of the citrus fruit. Here, citrus fruit is a grapefruit called the citrus paradisi (citrus paradisi), and since the extract itself is highly viscous, it is preferable to dilute with water and to use a dispersing agent such as natural glycerin and propylene glycol. . Since the extract of citrus paradish seed has bactericidal effects such as bactericidal and antimicrobial effects of bacteria and microorganisms, the bactericidal effect of the object to be cleaned can be expected when it is added as a bactericidal additive to the cleaning composition of the present invention. As another fungicide, you may mix | blend the natural fungicide obtained from tea leaves, a bamboo, etc.
[122] (4) Manufacturing Method of Cleaning Composition
[123] Since the cleaning composition of the present invention is almost all of the raw materials are powders or granular materials, and only if they are uniformly mixed, they can be easily produced in various formulations by various methods. In the simplest and most economical production method, the powdery or granular detergent composition of the present invention is prepared by stirring and mixing these powder raw materials with a known batch mixer.
[124] Because of its ease of use, it can be in tablet form or sheet form per use amount. Moreover, the cleaning composition of this invention can also be manufactured from the beginning as a concentrated liquid detergent by mixing powder raw material and water.
[125] On the other hand, in the case of producing the weak alkali inorganic salt cleaning liquid of the present invention by electrolyzing an aqueous sodium hydrogen carbonate solution stored in a washing tank, for example, in a circulation or batch type, re-contamination prevention containing the above-mentioned silicate or water-soluble polymer substance What is necessary is just to add a component etc. after separately in the form of powder or aqueous solution.
[126] (5) cleaning liquid
[127] The present invention is basically a medical washing method comprising an inorganic salt cleaning action component that forms an alkaline buffer system as the main cleaning action component and a recontamination prevention component that is washed with a cleaning liquid that substantially does not contain a surfactant. It is about. In addition, the presence of an enzyme for washing further in the cleaning liquid can further improve the washing performance.
[128] As described above, the alkaline inorganic salt in the present invention preferably contains an alkali metal bicarbonate salt, an alkali metal carbonate salt and / or an alkali metal silicate salt as main components, and in Japanese washing conditions, the alkaline cleaning salt of the present invention is alkaline. It is preferable to melt | dissolve at the density | concentration of about 1-2 g / L (0.1-0.2 weight%) as an inorganic salt total amount. The alkali metal bicarbonate salt and the alkali metal carbonate salt are preferably present in a molar number of 1: 7 to 1: 0.2, and the alkali bicarbonate metal salt and alkali metal silicate salt are in a molar ratio of 1: 1.2 to 1: 0.1. It is preferable to exist. Moreover, when these exist in a three component system, an alkali metal silicate salt can be substituted by the alkali metal carbonate salt from a viewpoint of washing power. On the other hand, the silicate is preferably sodium metasilicate pentahydrate from the viewpoint of pH, solubility, reduction in total amount of use, and production cost.
[129] 9.5-11 are preferable from a viewpoint of washing | cleaning power, a softening rate, etc., and, as for the pH which the washing | cleaning liquid (1g / L concentration) of this invention mainly determined by an alkaline inorganic salt buffer system, 10-10.6 are more preferable.
[130] Moreover, as for the total amount of the (organic) recontamination prevention component which is one main component in the inorganic washing | cleaning liquid of this invention, 0.01 g / L (0.001 weight%) or more is preferable. And when using the sodium metasilicate (pentahydrate) which also has the recontamination prevention performance 30-70 weight% of the total amount of a cleaning composition, it is 0.007 g / L (0.0007 weight%) or more as an organic type recontamination prevention component concentration contained in a washing liquid. can do.
[131] As in Japan, under general washing conditions such as low temperature washing with low hardness, the actual use concentration of the cleaning liquid according to the present invention is stored in a range of 0.5 to 5 g / L (0.05 to 0.5% by weight). On the other hand, the actual use concentration in such a range corresponds to the actual use concentration in the claims, and is diluted to about 0.5 g / L (0.05% by weight, equivalent to the concentration when 15 g of the detergent composition is dissolved in 30 L of washing water). Gin use concentration is used when washing lightly contaminated medical care, and increased use concentration to 5 g / L (0.5 wt%, equivalent to concentration when 150 g of detergent composition is dissolved in 30 L of washing water) For example, it is used when washing in an immersion washing or a high hardness washing water area, and in these low concentration and high concentration intermediate concentration areas, a suitable concentration is used depending on the amount of medical care to be washed, the capacity for washing water, and the like. And in this actual use concentration range, the washing | cleaning agent of this invention shows the washing | cleaning performance of about equivalent or more with existing laundry soap and synthetic detergent.
[132] Below, about the powder cleaning composition of the standard composition of this invention, the addition amount and pH relationship of a washing | cleaning liquid are shown.
[133] 0.5 to 5 g when dissolved in 30 liters of water using a cleaning composition having a blending ratio of 112 g of sodium carbonate, 60 g of sodium bicarbonate, 110 g of sodium metasilicate pentahydrate, and 18 g of other additives, and the total weight of the cleaning agent being 300 g. The pH value (25 degreeC) which each washing | cleaning liquid in each density | concentration in the range of / L (0.05-0.5 weight%) shows is as follows. In other words, 10.39, 0.15 weight% (input of powder detergent composition is 15 g / 30L) at 10.64, 0.15 weight% (injection amount of powder detergent composition is 45 g / 30L) 10.73, 0.20% by weight (the amount of the powder detergent composition is 60 g / 30L), 10.78, 0.25% by weight (the amount of the powder detergent composition is 75g / 30L), 10.79, 0.30% by weight (the amount of the powder detergent composition is 90g / 30L) At 10.80, 0.50% by weight (the dosage of the powder detergent composition is 150 g / 30 L) at 10.89.
[134] (Operation and Effects of the Invention)
[135] According to the present invention, it is a detergent composition which does not use a surfactant which has a doubt from the viewpoint of the safety to a human body, or the environmental burden reduction, or the use amount of surfactant drastically reduced, and it is the detergent which the enzyme and the bleach mixed, It is possible to provide the cleaning composition of the inorganic salt main component having the same or more cleaning power and ease of use, and in particular, excellent in recontamination prevention performance. Moreover, according to the medical washing method, the medical detergent composition, and the anti-contamination agent which concern on this invention, the consumer demand of modern Japan which contradicts the cleanliness orientation which dislikes dirt and the health orientation which dislikes the residue of the detergent component for the medical care at first glance. Both of these can be met at extremely high levels.
[136] When the bicarbonate and carbonate and / or silicate of the alkali metal are dissolved in water and set to a specific pH and concentration range, a cleaning effect such as saponification, decomposition, or the like of fat or oil contamination by the alkaline agent is obtained. In addition, since it is a buffer system in which bicarbonate coexists, a large amount of alkali functional salts of carbonate and / or silicate can be added, and thus the ionic strength of the cleaning solution is increased. Therefore, anion is adsorbed to both the solid contamination and the surface of the laundry, thereby reducing the electrical repulsive force. It acts, and solid contamination tends to fall from the surface of a laundry. In addition, in the conventional laundry system, such as calcium ions and magnesium ions contained in water, the hardness component which is a deterrent to cleaning power becomes carbonate, and colloidal calcium carbonate generated in the process of the generation or aggregation of carbonate is contaminated particles in the cleaning liquid. May be adsorbed to improve the cleaning performance.
[137] Silicates, in particular sodium metasilicate, generate colloids in aqueous solutions and have essentially the action of dispersing the inorganic contaminant particles into the cleaning liquid, thereby preventing the adsorption of contaminated particles to the fiber, that is, recontamination. When combining the cleaning composition which consists mainly of carbonate and bicarbonate with a silicate, it is possible to substitute with carbonate in arbitrary ratios, without impairing cleaning power.
[138] This main cleaning action is applied to the cleaning composition obtained by the inorganic salt, the surface tension lowering effect of methyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose, partially saponified polyvinyl alcohol, and the like. By adding a very small amount of water-soluble high molecular material with anti-pollution ability, the anti-contamination performance, which was the main cause of the dissemination of the alkaline inorganic salt detergent, is greatly improved, and the washing performance can be made at a practical level equivalent to that of the synthetic detergent. Can be. The water-soluble high molecular substance having the action of lowering the surface tension is particularly effective for chemical fibers such as polyester which are easily recontaminated and difficult to prevent, and by using other recontamination prevention components which also contain the sodium metasilicate. The addition amount of the whole recontamination prevention component can be made still lower.
[141] Hereinafter, the specific example which compared the cleaning composition or cleaning liquid of this invention with the conventional cleaning composition and its cleaning liquid is demonstrated. However, the specific numerical value shown below discloses one part of the washing | cleaning performance obtained by use of the cleaning composition of this invention illustratively, and is not intended to limit this invention. On the other hand, with respect to the examples or comparative examples relating to the cleaning power test disclosed in the present specification, the cleaning power may change depending on the difference in the lot number of the dirty cloth to be used. It is noted that there is a case where a simple comparison between numbers is not possible.
[142] (Cleaning force test 1)
[143] Prior to the description of the cleaning force test 1, the test conditions are revealed.
[144] Washing machine tap water (Fujisawa-shi city water supply, pH 7.5, EC19mS / m) of water temperature 20 degrees Celsius using Toshiba Corporation fully automatic washing machine (AW-C60VP, 6 kg type, water level setting 31 liters, towel 2 kg as load) The washing was performed for 12 minutes, rinsing once, and dehydration was performed for 5 minutes.
[145] Three artificial contaminant cloths (manufactured by ScientificServices S / D inc. USA, two kinds of cotton and blend) attached to this washing machine, and a contaminated cloth (EMPA101) with mineral oil and carbon black, olive oil Contaminated cloth with carbon black (EMPA106), contaminated cloth with blood (EMPA111), contaminated cloth with protein cacao (EMPA112), contaminated cloth with red wine (EMPA114), blood, milk and carbon Each of the three pieces of black stained cloth (EMPA116) was sewn onto a towel and washed. In addition, "washing rate" was computed by the following formula.
[146] Cleaning rate% = (whiteness of contaminated cloth after washing-whiteness of contaminated cloth before washing)
[147] ÷ (whiteness of uncontaminated dough-whiteness of contaminated cloth before washing) × 100
[148] Here, the "whiteness" averaged the measured value of 10 different front and back of each of the 3 soil cloths by the whiteness meter (CR-14, Whiteness Index Color Reader by Minolta Co., Ltd.).
[149] In addition, the cleaning power test disclosed in this specification adds that it is based on this test condition, unless there is particular notice.
[150] (Example 1)
[151] Washing agent which consists of each component composition of 9 g of sodium carbonate, 10 g of sodium bicarbonate, 22 g of sodium metasilicate (9-hydrate), 0.2 g of methyl cellulose, and 0.2 g of polyvinyl alcohol in 31 liters of tap water, and the total amount of the same component is 41.4 g It melt | dissolved and obtained the washing | cleaning liquid whose detergent concentration is 1.34 g / L, and pH is 10.6. The washing rate of each contaminant cloth before and after washing when wash | cleaned using this washing | cleaning liquid was measured. The results are shown in Table 15.
[152] (Example 2)
[153] It is composed of each component composition of 16 g of sodium bicarbonate, 40 g of sodium metasilicate (9 hydrates), 0.2 g of methyl cellulose, and 0.2 g of polyvinyl alcohol, and dissolves a detergent having a total amount of 56.4 g in 31 liters of tap water. Was 1.82 g / L, and the washing | cleaning liquid which pH was 10.6 was obtained. The washing rate of each contaminant cloth before and after washing when wash | cleaned using this washing | cleaning liquid was measured. The results are shown in Table 15.
[154] (Example 3)
[155] It is composed of each component composition of 18 g of sodium carbonate, 8 g of sodium bicarbonate, 0.2 g of methyl cellulose, and 0.2 g of polyvinyl alcohol in 31 liters of tap water, and dissolves a detergent having a total amount of 26.4 g of the same, and the detergent concentration is 0.85 g / L, A washing liquid having a pH of 10.3 was obtained. The washing rate of each contaminant cloth before and after washing when wash | cleaned using this washing | cleaning liquid was measured. The results are shown in Table 15.
[156] (Example 4)
[157] The cleaning rate of the contaminated cloth was measured in the same manner as in Example 1 except that 0.3 g of protease as an enzyme, 0.1 g of cellulase and 0.6 g of sodium sulfite as a reducing agent were added to the washing solution of Example 1, respectively. did. The results are shown in Table 15.
[158] (Example 5)
[159] In addition to the rinse solution of Example 1, 0.3 g of protease as enzyme, 0.1 g of cellulase, 0.6 g of sodium sulfite as reducing agent, and 6 g of sodium percarbonate as bleach were added and dissolved in the same manner as in Example 1 The cleaning rate of the contaminated cloth was measured. The results are shown in Table 15.
[160] (Comparative Example 1)
[161] As a comparative example of Examples 1 to 5, each component composition of 18 g of sodium carbonate and 8 g of sodium bicarbonate was dissolved in 31 liters of tap water, and the total amount of the components was dissolved in 26 g, so that the concentration of the detergent was 0.84 g / L and the pH was A washing solution of 10.4 was obtained. Using this cleaning liquid, the cleaning rate of the contaminated cloth was measured in the same manner as in Example 1. The results are shown in Table 15.
[162] (Comparative Example 2)
[163] As a comparative example of Examples 1 to 5, a contaminated cloth was prepared in the same manner as in Example 1 using a washing liquid (cleaner concentration 1 g / L, manufactured by Miyoshi Soap Co., Ltd.) in which commercially available powdered soap was dissolved in tap water at a standard concentration. The washing rate of was measured. The results are shown in Table 15.
[164] (Comparative Example 3)
[165] As a comparative example of Examples 1 to 5, a commercially available liquid synthetic detergent was diluted and dissolved in tap water at a standard concentration (liquid Atacku, 20 mL / 31 L of detergent concentration, manufactured by Cao Corporation, without any combination of enzyme and bleach). , And the cleaning rate of the contaminated cloth was measured in the same manner as in Example 1. The results are shown in Table 15.
[166] (Comparative Example 4)
[167] As a comparative example of Examples 1 to 5, using a washing solution (new beads, detergent concentration 0.8 g / L, manufactured by Cao, Inc., enzymes and bleach mixture) in which commercial powder synthetic detergent was dissolved in tap water at a standard concentration, In the same manner as in 1, the cleaning rate of the contaminated cloth was measured. The results are shown in Table 15.
[168] (Comparative Example 5)
[169] As comparative examples of Examples 1 to 5, using a cleaning solution (attakku, 0.65 g / L, manufactured by Cao Corporation, enzymes and bleach mixture) in which commercially available powdered synthetic detergent was dissolved in tap water at a standard concentration, Similarly, the cleaning rate of the contaminated cloth was measured. The results are shown in Table 15.
[170] Table 15
[171]
[172] As is clear even when the cleaning rates of Examples 1 to 5 and the cleaning rates of Comparative Examples 2 to 5 are evident, all of the cleaning solutions containing the recontamination prevention component as the inorganic salt of the present embodiment are washed with commercially available surfactants. The cleaning power is approximately equivalent to or higher than that of the laundry soap or the synthetic detergent which is the main ingredient. Among these, when comparing Example 4, Example 5, and Comparative Examples 2-5, the thing of Example 4, Example 5 which added the enzyme, the reducing agent, and the bleach further is equivalent to the general laundry soap or synthetic detergent. Or it demonstrates that the cleaning power more than that, especially the cleaning power for protein contamination is excellent.
[173] On the other hand, when Examples 1-3 are compared with Comparative Example 1, the water-soluble high molecular substance which has surface tension reducing effect, such as methylcellulose and polyvinyl alcohol which were added in the Example, wash | cleaning rate in this test of single washing | cleaning Esau hardly recognizes the effect.
[174] In addition, when Example 1, Example 2, and Example 3 are compared, even if sodium metasilicate and sodium carbonate are substituted, it can understand that washing | cleaning rate is substantially equivalent.
[175] (Recontamination test 1)
[176] Recontamination test 1 was implemented under the test conditions of the following description, and the recontamination prevention effect was confirmed.
[177] (Recontamination test condition)
[178] Washing machine uses two tank type washing machine (ES-25E, water level setting 30 liters, towel 1.5 kg as load) made by Sharp Co., Ltd. in tap water (Fujisawa-shi city water supply, pH 7.2, EC15.5mS / m) of water temperature 20 degrees Celsius Washing was performed for 10 minutes, rinsing with running water for 4 minutes, and dehydration for 5 minutes.
[179] 0.45 g of ink was dripped in this washing machine as pseudo contamination of recontamination, and each piece of cotton and polyester white cloth (5 square cm) was sewn onto a towel, and washed with the following contamination cloth.
[180] Recontamination evaluation was performed by measuring the whiteness before and after washing of each of the above-mentioned cotton and the white cloth (5 square cm) of polyester. The recontamination degree as an evaluation value was made into the value which subtracted the whiteness before washing from the whiteness after washing. When the recontamination degree is positive, it means that the side after washing is whiter, and when it is negative, it means that it is recontaminated after washing and the whiteness is reduced. Therefore, if recontamination degree is zero or a positive value (however, -1 or more in case of polyester), it can be judged that recontamination prevention performance is satisfactory practically.
[181] In addition, the recontamination test disclosed in this specification adds that what was performed based on this test condition unless there is particular notice.
[182] (Example 6)
[183] It wash | cleaned using the washing | cleaning liquid obtained in Example 1, and the recontamination degree at this time was calculated | required by calculation. The results are shown in Table 16.
[184] (Example 7)
[185] Recontamination was evaluated on the conditions similar to Example 6 using the washing | cleaning liquid obtained in Example 2. The results are shown in Table 16.
[186] (Example 8)
[187] Recontamination was evaluated on the conditions similar to Example 6 using the washing | cleaning liquid obtained in Example 3. The results are shown in Table 16.
[188] (Comparative Example 6)
[189] As a comparative example of Examples 6-8, recontamination was evaluated on the conditions similar to Example 6 using the washing | cleaning liquid obtained in Comparative Example 1. The results are shown in Table 16.
[190] (Comparative Example 7)
[191] As a comparative example of Examples 6-8, it consists of each component composition of 9 g of sodium carbonate, 10 g of sodium bicarbonate, and 22 g of sodium metasilicates (9-hydrate) in 31 liters of tap water, and the detergent of 41 g of total amounts of these components is melt | dissolved, A washing liquid having a concentration of 1.32 g / L and a pH of 10.6 was obtained. Recontamination was evaluated on the conditions similar to Example 6 using this washing | cleaning liquid. The results are shown in Table 16.
[192] (Comparative Example 8)
[193] As comparative examples of Examples 6 to 8, recontamination was evaluated under the same conditions as in Example 6 using the cleaning liquid of Comparative Example 3. The results are shown in Table 16.
[194] Table 16
[195]
[196] As is also apparent from these results, the re-contamination degree is large and not practical unless the water-soluble polymer material is added (see Comparative Example 6, Comparative Example 7), but the cleaning solutions of Examples 6 to 8 to which the water-soluble polymer material is added are most reusable. Even if the pollution prevention effect is low (Example 8), the recontamination prevention performance of Comparative Example 6 and Comparative Example 7 or more is exhibited.
[197] Comparing Examples 6-8, it turns out that recontamination prevention performance becomes high, so that content of sodium metasilicate in a washing | cleaning agent increases.
[198] (Recontamination test 2)
[199] (Example 9)
[200] It consists of each component composition of 9 g of sodium carbonate, 10 g of sodium bicarbonate, 22 g of sodium metasilicate (9-hydrate), and 0.4 g of methyl cellulose in 31 liters of tap water, and dissolves the detergent whose total amount is 41.4 g, and the detergent concentration is 1.34 g. / L and the washing | cleaning liquid which pH is 10.6 were obtained. Recontamination was evaluated on the conditions similar to Example 6 using this washing | cleaning liquid. The results are shown in Table 17.
[201] (Example 10)
[202] It consists of each component composition of 9 g of sodium carbonate, 10 g of sodium bicarbonate, 22 g of sodium metasilicate (9 hydrates), and 0.4 g of polyvinyl alcohol in 31 liters of tap water, and dissolves the detergent of 41.4 g of the total amount, and the detergent concentration is 1.34. The washing | cleaning liquid which g / L and pH is 10.6 was obtained. Recontamination was evaluated on the conditions similar to Example 6 using this washing | cleaning liquid. The results are shown in Table 17.
[203] (Example 11)
[204] It consists of each component composition of 9 g of sodium carbonate, 10 g of sodium bicarbonate, 22 g of sodium metasilicate (9-hydrate), and 0.4 g of hydroxypropyl cellulose in 31 liters of tap water, and dissolves the detergent whose total amount is 41.4 g, The detergent concentration is A washing liquid having 1.34 g / L and a pH of 10.7 was obtained. Recontamination was evaluated on the conditions similar to Example 6 using this washing | cleaning liquid. The results are shown in Table 17.
[205] (Example 12)
[206] In 31 liters of tap water, 9g of sodium carbonate, 10g of sodium bicarbonate, 22g of sodium metasilicate (9-hydrate), 0.2g of hydroxypropyl cellulose, 0.2g of polyethylene glycol, and a detergent having a total amount of 41.6g are dissolved. Thus, a washing liquid having a detergent concentration of 1.34 g / L and a pH of 10.7 was obtained. Recontamination was evaluated on the conditions similar to Example 6 using this washing | cleaning liquid. The results are shown in Table 17.
[207] (Example 13)
[208] In 31 liters of tap water, 9 g of sodium carbonate, 10 g of sodium bicarbonate, 22 g of sodium metasilicate (9-hydrate), LT 0.45 g, and 0.15 g of carboxymethylcellulose were dissolved, and a total amount of 41.6 g of the same component was dissolved. The washing | cleaning liquid whose detergent concentration is 1.34 g / L and pH is 10.6 was obtained. Recontamination was evaluated on the conditions similar to Example 6 using this washing | cleaning liquid. The results are shown in Table 17.
[209] (Comparative Example 9)
[210] As a comparative example of Examples 9-13, it consists of each component composition of 9 g of sodium carbonate, 10 g of sodium bicarbonate, and 22 g of sodium metasilicates (9-hydrate) in 31 liters of tap water, The detergent of 41 g of total amounts of the said components is melt | dissolved, A washing liquid having a concentration of 1.32 g / L and a pH of 10.6 was obtained. Recontamination was evaluated on the conditions similar to Example 6 using this washing | cleaning liquid. The results are shown in Table 17.
[211] Table 17
[212]
[213] When the water-soluble polymer substance is added alone, as is apparent from the results of the present recontamination test 2 comparing the types and amounts of the recontamination inhibitors with various combinations of the inorganic salt main ingredient compositions. Considering the balance between cotton and chemical fibers (polyester), it can be seen that polyvinyl alcohol (see Example 10) exhibits the best recontamination prevention performance.
[214] (Cleaning force test 2)
[215] The cleaning power test 2 was conducted under the test conditions according to the cleaning power test 1, and the cleaning performance was compared and confirmed between the conventional synthetic detergent and the laundry soap.
[216] (Example 14)
[217] The cleaning rate of each contaminant cloth before and after washing when washing with 30 liters of washing water obtained by dissolving 30 g of the cleaning agent A (enzyme-free formulation) of the present invention having 31 liters of tap water in 30 L of washing water. Was measured. The results are shown in Table 18.
[218] Composition of Cleaner A (Enzyme-free Blending) of the Invention
[219] 10.5 g sodium carbonate
[220] 8.0 g sodium bicarbonate
[221] Sodium Metasilicate 11g
[222] PVA 0.25g
[223] HPMC 0.25g
[224] Total amount 30.0 g
[225] (Example 15)
[226] The washing rate of each contaminant cloth before and after washing when washing with 30 liters of washing water obtained by dissolving 30 g of the washing agent B (enzyme formulation) of the present invention composed of the following components composition in 31 liters of tap water Measured. The results are shown in Table 18.
[227] Composition of the Invention Cleaner B (Enzyme Blended)
[228] 10.0 g of sodium carbonate
[229] Sodium bicarbonate 7.8g
[230] Sodium metasilicate 10.8 g
[231] PVA 0.2 g
[232] HPMC 0.2g
[233] 0.2 g of protease
[234] 0.2 g of cellulase
[235] 0.6 g sodium sulfite
[236] Total amount 30.0 g
[237] (Comparative Example 10)
[238] As a comparative example of Example 14 and Example 15, it carried out similarly to Example 14 using the washing | cleaning liquid (cleaner concentration 20mL / 31L, enzyme mix) which diluted and dissolved commercially available liquid synthetic detergent in tap water at the standard concentration. The washing rate was measured. The results are shown in Table 18.
[239] (Comparative Example 11)
[240] As a comparative example of Examples 14 and 15, contamination was carried out in the same manner as in Example 14 using a washing solution (0.65 g / L, enzyme and fluorescent brightener combination) in which a commercially available powdered synthetic detergent was dissolved in tap water at a standard concentration. The washing rate of the cloth was measured. The results are shown in Table 18.
[241] (Comparative Example 12)
[242] As a comparative example of Example 14 and Example 15, the cleaning rate of the contaminated cloth was carried out in the same manner as in Example 14, using a cleaning liquid (for atopy patients, 9% surfactant blend) in which commercial liquid detergent was dissolved in tap water at a standard concentration. Was measured. The results are shown in Table 18.
[243] (Comparative Example 13)
[244] As a comparative example of Examples 14 and 15, the cleaning rate of the contaminated cloth was measured in the same manner as in Example 14, using a washing solution (cleaning solution concentration of 1 g / L) in which commercially available powdered soap was dissolved in tap water at a standard concentration. did. The results are shown in Table 18.
[245] Table 18 shows the results of the cleaning power test performed on Examples 14 and 15 and Comparative Examples 10 to 13.
[246] Table 18
[247]
[248] As is apparent from the comparison between the cleaning rates of Examples 14 and 15 and the cleaning rates of Comparative Examples 10 to 13, all of the cleaning solutions containing the recontamination prevention component as the main salt of the inorganic salt of this example are commercially available interfaces. The cleaning power is approximately equivalent to or higher than that of laundry soap or synthetic detergent having the active agent as a washing ingredient. Among these, when comparing Example 14, Example 15, and Comparative Examples 10-13, the thing of Example 15 which added the enzyme and the reducing agent comprehensively performed the washing performance equivalent or more than the conventional laundry soap or synthetic detergent. It turns out that it is excellent in the washing power especially for protein contamination.
[249] (Recontamination test 3)
[250] Recontamination test 3 was conducted under the test conditions according to recontamination test 1, and the recontamination prevention performance was compared and confirmed between the existing synthetic detergent and laundry soap.
[251] (Example 16)
[252] 30 g of detergent A (enzyme-free formulation) of the present invention having 31 g of tap water and the same ingredient composition as in Example 14 was washed with a washing solution obtained by dissolving in 30 L of washing water, and the recontamination degree at this time was calculated by calculation. Saved. The results are shown in Table 19.
[253] (Example 17)
[254] 30 g of detergent B (enzyme formulation) of the present invention having 31 g of tap water and the same ingredient composition as in Example 15 was washed with a washing solution obtained by dissolving in 30 L of washing water, and the recontamination degree at this time was calculated by calculation. . The results are shown in Table 19.
[255] (Comparative Example 14)
[256] As a comparative example of Example 16 and Example 17, it wash | cleaned using the washing | cleaning liquid similar to the comparative example 10, and the recontamination degree at this time was calculated | required by calculation. The results are shown in Table 19.
[257] (Comparative Example 15)
[258] As a comparative example of Example 16 and Example 17, it wash | cleaned using the washing | cleaning liquid similar to the comparative example 11, and the recontamination degree at this time was calculated | required by calculation. The results are shown in Table 19.
[259] (Comparative Example 16)
[260] As a comparative example of Example 14 and Example 15, it wash | cleaned using the washing | cleaning liquid similar to the comparative example 12, and the recontamination degree at this time was calculated | required by calculation. The results are shown in Table 19.
[261] (Comparative Example 17)
[262] As a comparative example of Example 14 and Example 15, it wash | cleaned using the washing | cleaning liquid similar to the comparative example 13, and the recontamination degree at this time was calculated | required by calculation. The results are shown in Table 19.
[263] Table 19
[264]
[265] PVA (polyvinyl alcohol) and HPMC (selected on the basis of the findings obtained by performing performance evaluation tests assuming the use of various or recontamination prevention materials alone or in combination, on the premise of being used in combination with the inorganic salt cleaner of the present invention) The cleaning solution of the present invention containing the recontamination inhibitor for the combination of hydroxypropyl methyl cellulose), as is apparent from the results of the recontamination test 3, regardless of the presence or absence of the enzyme combination, cotton and chemical fibers ( It can be seen that both of the polyesters) exhibit approximately the same or more recontamination prevention performance as laundry soaps or synthetic detergents using commercially available surfactants as main components of washing.
[266] (COD / BOD analysis test)
[267] Results of the analysis test results of COD and BOD were performed on the cleaning liquid obtained by dissolving the cleaning agent of the present invention in water at 1 g / L (0.1 wt%), which is the actual concentration, and the cleaning liquid obtained by dissolving commercial powder synthetic detergent in water at a standard concentration. Table 20 shows. In addition, this analysis test was performed based on the "factory drainage test method" of JIS.
[268] Table 20
[269]
[270] From the analysis test results in Table 20, the cleaning liquid obtained from the cleaning agent of the present invention was approximately 1/20 in both COD and BOD, compared to the cleaning liquid obtained from commercially available powdered synthetic detergent, and therefore, the cleaning agent of the present invention instead of the conventional synthetic detergent. When it is used for medical washing, it turns out that the drastic reduction of environmental burden can be expected.
[271] (Fish toxicity test)
[272] As aquatic organisms, a squid is used, and as a breeding water of this scorpion, a washing liquid obtained by dissolving a commercial powder synthetic detergent in water (standard concentration: 0.7 g / L (0.07 wt%)) and powdered pure soap are dissolved in water. The washing liquid obtained by dissolving the washing agent of the present invention in water (standard concentration: 1 g / L (0.1 wt%)) and the washing liquid obtained by dissolving the washing agent of the present invention (standard concentration: 1 g / L (0.1 wt%)) as standard for each washing liquid. Table 10 shows the results of a fish toxicity test in which 10 washes prepared at each concentration of fold dilution and 25-fold dilution were prepared, and 10 shoots were killed at a rate of 1 per 1 L in each wash solution, and the change in survival rate was observed in Table 21. Shown in
[273] Table 21
[274]
[275] From the results of the fish toxicity test of Table 21, it can be said that the washing | cleaning liquid of this invention is extremely stable also about aquatic organisms compared with the washing | cleaning liquid obtained from commercially available powder synthetic detergent or powdered soap.
[276] (Specification of use drug)
[277] The following was used about the use drug disclosed in this specification.
[278] Sodium Carbonate: Soda Ash Tokuyama Co., Ltd.
[279] Sodium bicarbonate: Sodium bicarbonate Tosoh Co., Ltd.
[280] Sodium metasilicate: Sodium metasilicate pentahydrate 28 to 30% Na ₂ O, 27 to 29% SiO ₂ Nippon Chemical Co., Ltd.
[281] Sodium sulfite: Sodium sulfite anhydrous Daito Chemical Co., Ltd.
[282] Methyl Cellulose: Metoroz SM MC400 Shin-Etsu Chemical Co., Ltd.
[283] Hydroxypropyl cellulose: HPC M-type Toguyama Co., Ltd.
[284] Hydroxypropylmethylcellulose: methorose SH SEB-04T Shin-Etsu Chemical Co., Ltd.
[285] Hydroxyethylmethyl cellulose: methorose SE SNB-30T Shin-Etsu Chemical Co., Ltd.
[286] Polyvinyl alcohol: Pobaru PA-05S Shin-Etsu Chemical Co., Ltd.
[287] Degree of polymerization 3500 partial saponification
[288] Degree of polymerization 1000 partial saponification
[289] Polymerization degree 500 partial saponification Wako Pure Chemicals Co., Ltd. reagent
[290] Polypropylene Glycol:
[291] Triol molecular weight 4000 Wako Pure Chemical Industries, Ltd.
[292] Diol molecular weight 3000 Wako Pure Chemical Industries, Ltd.
[293] Pluronic: Adeka Pluronic (L31, L34, L61, L64, F68, L101, P103, F108) Asahi Denka Kogyo Co., Ltd.
[294] Enzyme 1: Protease Properase 1000E Nagase Kemutekkus Co., Ltd.
[295] Enzyme 2: Cellulase celluzyme 0.7T Novosimus Japan
[296] Surfactants:
[297] Nonion (ot-221, lt-221) japan oil company
[298] Laurylamide propyl acetate betaine PB-30L Asahi Denka Kogyo Co., Ltd.
[299] Polyglycerol Fatty Acid Ester CPG-150 Asahi Denka Kogyo Co., Ltd.
[300] Polyethylene glycol oleate oeg-106 asahidenka industry
[301] Other :
[302] Ethylene Glycol Wako Pure Chemical Co., Ltd.
[303] Polyethylene Glycol PEG-6000 Molecular Weight 6000
[304] PEG-400 Molecular Weight 400
[305] Wako Pure Chemical Industry Co., Ltd.
[306] Hydroxyethyl Cellulose SP-400 Daicel Chemical Industry Co., Ltd.
[307] Carboxymethyl cellulose WS-D etherification degree 0.6-0.7
[308] BSH-12 etherification degree 0.65 to 0.75
[309] Daiichi Pharmaceutical Co., Ltd.
[310] Polyvinylpyrrolidone (PVP) Average Molecular Weight 33000
[311] Average molecular weight 360000
[312] Wako Pure Chemical Industry Co., Ltd.
[313] Sodium polyacrylate average molecular weight 2700 ~ 7500
[314] The cleaning composition of the present invention is a cleaning composition containing alkaline inorganic salt as a main component of washing and substantially free of a surfactant, and has a cleaning power equivalent to or higher than that of a laundry soap or a synthetic detergent containing a conventional surfactant as a main component. And ease of use.
[315] The present invention described above clearly exists in various kinds of identity. Such variety is not to be regarded as a departure from the intent and scope of the invention, and all such modifications apparent to those skilled in the art are included within the technical scope of the claims relating to the present invention.

权利要求:
Claims (45)
[1" claim-type="Currently amended] A medical washing method comprising washing an inorganic salt which forms an alkaline buffer system as a main cleaning action component and further washing with a cleaning liquid containing at least a recontamination prevention component.
[2" claim-type="Currently amended] Medical washing method comprising washing with a washing solution prepared so that the surface tension is 58 dyn / cm or less by using the inorganic salt forming the alkaline buffer system as a main cleaning action component and further containing a recontamination prevention component. .
[3" claim-type="Currently amended] By using the inorganic salt which forms an alkaline buffer system as a main washing | cleaning action component, and also containing a recontamination prevention component, it is the washing | cleaning liquid in which surface tension became 58 dyn / cm or less and the recontamination prevention property of hydrophobic fiber improved. Washing by medical treatment method characterized by the above-mentioned.
[4" claim-type="Currently amended] Medical washing comprising an inorganic salt forming an alkaline buffer system as a main cleaning action component, and further including at least a recontamination prevention component, and washing with a cleaning solution prepared to have a pH of 9.5 to 11. Way.
[5" claim-type="Currently amended] It is a washing | cleaning liquid which uses the inorganic salt which forms an alkaline buffer system as a main washing | cleaning action component, and also contains at least a recontamination prevention component, and is prepared so that surface tension may be 58 dyn / cm or less and pH is set to 9.5-11. Washing by medical treatment method characterized by the above-mentioned.
[6" claim-type="Currently amended] It is a washing | cleaning liquid which makes the inorganic salt which forms an alkaline buffer system the main washing | cleaning action component, and also contains at least a recontamination prevention component, The surface tension is 58 dyn / cm or less, pH is 9.5-11, A medical washing method comprising washing with a cleaning liquid having improved antifouling properties.
[7" claim-type="Currently amended] A washing method for medical treatment in which an inorganic salt forming an alkaline buffer system is contained as a main cleaning action component and a cleaning solution obtained through a step of containing a recontamination prevention component. It is produced | generated by decomposing, The medical washing method characterized by the above-mentioned.
[8" claim-type="Currently amended] The surface tension of the cleaning liquid according to any one of claims 1 to 7, wherein the recontamination prevention component contains at least one or more substances having a function of lowering the surface tension of the cleaning liquid. The washing method characterized in that the lowered.
[9" claim-type="Currently amended] The method according to any one of claims 1, 3, 4, 6, and 7, wherein the recontamination preventing component has a function of lowering the surface tension of the cleaning liquid, and recontamination of hydrophobic fibers. Washing method characterized by containing at least 1 type of substance which has the effect | action which improves prevention property, and reduces the surface tension of the said washing | cleaning liquid to 58 dyn / cm or less, and improves recontamination prevention property of hydrophobic fiber. .
[10" claim-type="Currently amended] The washing method according to claim 8, wherein the substance having the action of lowering the surface tension of the cleaning liquid in the recontamination prevention component is a water-soluble polymer material.
[11" claim-type="Currently amended] The washing method according to claim 9, wherein the substance which has a function of lowering the surface tension of the cleaning liquid in the recontamination preventing component and improves the recontamination preventing property of the hydrophobic fiber is a water-soluble polymer material.
[12" claim-type="Currently amended] The said water-soluble high molecular substance contains at least any of acetyl group, a methoxy group, a hydroxypropyl group, and polypropylene glycol as a hydrophobic group, and also contains a hydroxyl group as a hydrophilic group. How to wash.
[13" claim-type="Currently amended] The washing method according to any one of claims 10 to 12, wherein the water-soluble high molecular material is nonionic.
[14" claim-type="Currently amended] The washing method according to any one of claims 10 to 13, wherein the average molecular weight of the water-soluble high molecular material is 1000 or more and 500,000 or less.
[15" claim-type="Currently amended] 15. The method according to any one of claims 10 to 14, wherein the water-soluble polymer material is methyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose, partially saponified polyvinyl alcohol, polypropylene glycol, A washing method comprising at least one member selected from the group consisting of polyoxyethylene polyoxypropylene block copolymers.
[16" claim-type="Currently amended] The washing method according to any one of claims 9 to 15, wherein a component concentration of the anti-recontamination component in the cleaning liquid is at least 0.007 g / L or more.
[17" claim-type="Currently amended] The washing method according to any one of claims 1 to 16, wherein the washing liquid is further added with a washing enzyme.
[18" claim-type="Currently amended] A medical cleaning composition comprising an inorganic salt that forms an alkaline buffer system as a main cleaning action component, and further contains at least a recontamination prevention component.
[19" claim-type="Currently amended] A cleaning composition comprising an inorganic salt which forms an alkaline buffer system as a main cleaning action component, and further contains at least a recontamination prevention component, and the surface tension of the cleaning liquid obtained by dissolving the cleaning composition in water at an actual use concentration is 58 dyn / cm. Medical cleaning composition characterized by the following.
[20" claim-type="Currently amended] A cleaning composition comprising an inorganic salt that forms an alkaline buffer system as a main cleaning action component and further contains a recontamination prevention component, and the surface tension of the cleaning solution obtained by dissolving the cleaning composition in water at an actual use concentration is 58 dyn / cm or less. And a cleaning liquid having improved recontamination prevention property of the hydrophobic fiber is obtained.
[21" claim-type="Currently amended] An inorganic salt forming an alkaline buffer system is a main cleaning action component, and further contains at least a recontamination prevention component, and the pH of the cleaning liquid obtained by dissolving the cleaning composition in water at an actual use concentration is 9.5 to 11. Medical detergent composition, characterized in that.
[22" claim-type="Currently amended] A cleaning composition comprising an inorganic salt which forms an alkaline buffer system as a main cleaning action component, and further contains at least a recontamination prevention component, and the surface tension of the cleaning liquid obtained by dissolving the cleaning composition in water at an actual use concentration is 58 dyn / cm. Hereinafter, furthermore, pH is 9.5-11, The medical cleaning composition characterized by the above-mentioned.
[23" claim-type="Currently amended] The cleaning composition according to any one of claims 19, 20, and 22, wherein the substance having a function of lowering the surface tension of the cleaning liquid in the recontamination prevention component is a water-soluble polymer material.
[24" claim-type="Currently amended] The cleaning composition according to claim 23, wherein the water-soluble high molecular substance contains at least any one of an acetyl group, a methoxy group, a hydroxypropyl group, and a polypropylene glycol as a hydrophobic group, and further contains a hydroxyl group as a hydrophilic group.
[25" claim-type="Currently amended] 25. The cleaning composition according to claim 23 or 24, wherein the water-soluble high molecular material is nonionic.
[26" claim-type="Currently amended] The cleaning composition according to any one of claims 23 to 25, wherein a molecular weight of the water-soluble high molecular material is 1000 or more and 500,000 or less.
[27" claim-type="Currently amended] 27. The method according to any one of claims 23 to 26, wherein the water-soluble high molecular material is methyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose, partially saponified polyvinyl alcohol, polypropylene glycol, A cleaning composition comprising at least one member selected from the group consisting of polyoxyethylene polyoxypropylene block copolymers.
[28" claim-type="Currently amended] The cleaning agent according to any one of claims 18 to 27, wherein the inorganic salt comprises an alkali metal bicarbonate salt, an alkali metal carbonate salt or an alkali metal silicate salt, and the total amount thereof is 90% by weight or more of the total amount of the cleaning composition. Composition.
[29" claim-type="Currently amended] The cleaning composition according to claim 28, wherein the composition ratio of the number of moles of the alkali metal bicarbonate salt to the number of moles of the alkali metal carbonate salt is 1: 7 to 1: 0.2.
[30" claim-type="Currently amended] The cleaning composition according to claim 28, wherein the composition ratio of the number of moles of the alkali metal bicarbonate salt to the number of moles of the alkali metal silicate salt is 1: 1.2 to 1: 0.1.
[31" claim-type="Currently amended] 28. The inorganic salt according to any one of claims 18 to 27, wherein the inorganic salt is composed of three kinds of alkali bicarbonate metal salts, alkali carbonate metal salts, and alkali silicate metal salts, and the total amount thereof is 90% by weight or more of the total amount of the cleaning composition. Cleaning composition.
[32" claim-type="Currently amended] The cleaning composition according to claim 31, wherein the content of the alkali silicate metal salt in the total amount of the cleaning composition is 20 to 90% by weight, preferably 30 to 70% by weight.
[33" claim-type="Currently amended] 33. The cleaning composition according to any one of claims 18 to 32, wherein the total amount of the material as the recontamination prevention component is 10% by weight or less of the total amount of the cleaning composition.
[34" claim-type="Currently amended] The cleaning composition according to any one of claims 18 to 33, further comprising a washing enzyme and a reducing agent for preventing inactivation of the enzyme, if necessary.
[35" claim-type="Currently amended] The cleaning composition according to any one of claims 18 to 34, further comprising an oxygen-based bleach as an additive.
[36" claim-type="Currently amended] A main anti-fouling agent is used in combination with a medical laundry cleaning liquid obtained from an inorganic salt forming an alkaline buffer system, and has a function of reducing the surface tension of the cleaning solution to 58 dyn / cm or less.
[37" claim-type="Currently amended] The main cleaning action component is used in combination with a cleaning solution for medical laundry obtained from an inorganic salt forming an alkaline buffer system, and has a function of reducing the surface tension of the cleaning solution to 58 dyn / cm or less, and also prevents recontamination of hydrophobic fibers. Recontamination prevention agent which has the effect | action which improves.
[38" claim-type="Currently amended] The main cleaning action component is used in combination with a cleaning solution for medical laundry prepared so as to have a pH of 9.5 to 11, obtained from an inorganic salt forming an alkaline buffer system, and has an effect of lowering the surface tension of the cleaning solution to 58 dyn / cm or less. Recontamination inhibitor, characterized in that.
[39" claim-type="Currently amended] The main cleaning action component is used in combination with a cleaning solution for medical laundry prepared so as to have a pH of 9.5 to 11, obtained from an inorganic salt forming an alkaline buffer system, and has a function of lowering the surface tension of the cleaning solution to 58 dyn / cm or less. And an anti-contamination agent, which has an effect of improving re-contamination prevention property of hydrophobic fibers.
[40" claim-type="Currently amended] 40. The recontamination inhibitor according to any one of claims 36 to 39, wherein the substance having a function of lowering the surface tension of the cleaning liquid to 58 dyn / cm or less is a water-soluble high molecular substance.
[41" claim-type="Currently amended] 40. The material according to claim 37 or 39, wherein the material having a function of lowering the surface tension of the cleaning liquid to 58 dyn / cm or less and having a function of improving recontamination prevention of hydrophobic fibers is a water-soluble polymer material. Recontamination inhibitor, characterized in that.
[42" claim-type="Currently amended] The water-soluble high molecular substance according to claim 40 or 41, wherein the water-soluble high molecular substance contains at least any one of an acetyl group, a methoxy group, a hydroxypropyl group and a polypropylene glycol as a hydrophobic group, and further contains a hydroxyl group as a hydrophilic group. Recontamination inhibitor.
[43" claim-type="Currently amended] 43. The recontamination inhibitor according to any one of claims 40 to 42, wherein the water-soluble high molecular material is nonionic.
[44" claim-type="Currently amended] The antifouling agent according to any one of claims 40 to 43, wherein the molecular weight of the water-soluble high molecular material is 1000 or more and 500,000 or less.
[45" claim-type="Currently amended] 45. The method according to any one of claims 40 to 44, wherein the water-soluble high molecular material is methyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose, partially saponified polyvinyl alcohol, polypropylene glycol, Recontamination prevention agent characterized by containing 1 or more types chosen from the group which consists of a polyoxyethylene polyoxypropylene block copolymer.

类似技术:

---

公开号 | 公开日 | 专利标题

---

US7922828B2|2011-04-12|Cleaning compositions containing water soluble magnesium compounds and methods of using them

---

AU2010209328B2|2015-07-02|Development of an aluminum hydroxycarboxylate builder

---

CA2433355C|2010-05-25|Methods and compositions for cleaning, rinsing, and antimicrobial treatment of medical equipment

---

US7922827B2|2011-04-12|Cleaning compositions containing water soluble magnesium compounds and methods of using them

---

US6693069B2|2004-02-17|Disinfecting compositions and processes for disinfecting surfaces

---

JP4966020B2|2012-07-04|Sterilization and cleaning composition and method of use for sterilizing and / or cleaning hard surfaces

---

JP5567348B2|2014-08-06|Fast-dissolving solid detergent

---

JP4621175B2|2011-01-26|Dishwashing system and dishwashing method containing nonionic surfactant having washing and coating functions

---

US6686324B2|2004-02-03|Low-foaming hydrogen peroxide cleaning solution for organic soils

---

DE60102318T2|2004-08-05|Detergent composition and method of making the composition

---

JP4094661B2|2008-06-04|Rinsing method with percarboxylic acid

---

JP4098357B2|2008-06-11|Rinsing method with sanitary treatment

---

EP1423497B1|2007-09-12|Thickened toilet bowl cleaner

---

CN104893870B|2018-10-02|A kind of domestic bowl-washing detergent and preparation method thereof with degerming

---

EP2699660B1|2015-08-12|Calcium sequestering composition

---

CN1103364C|2003-03-19|Germicidal dishwashing detergent compositions

---

JP4846268B2|2011-12-28|Liquid detergent composition for clothing

---

DE60120377T2|2007-05-10|Polymers for preventing deposits of calcium phosphate and calcium carbonate in dishwashing machines

---

RU2598350C2|2016-09-20|Cleaner and disinfectant for medical instruments

---

JP5036962B2|2012-09-26|Disinfectant composition for automatic washing machine

---

US9873855B2|2018-01-23|Cleaning formulations and uses thereof

---

CN103890160B|2017-03-08|A kind of liquid hard-surface antibacterial cleansing composition

---

RU2606123C2|2017-01-10|Calcium binding composition

---

CN100503799C|2009-06-24|Cleaning agent for washing machine tank

---

US8389460B2|2013-03-05|Clothes washing method and surfactant-free detergent composition used for the same

同族专利:

---

公开号 | 公开日

---

KR100533123B1|2005-12-01|

---

AU2106102A|2002-06-18|

---

JPWO2002046348A1|2004-04-08|

---

US7553807B2|2009-06-30|

---

TWI227733B|2005-02-11|

---

CA2430374C|2011-01-11|

---

US20040082490A1|2004-04-29|

---

EP1340805A1|2003-09-03|

---

HK1062833A1|2006-08-11|

---

US7407924B2|2008-08-05|

---

CN1479784A|2004-03-03|

---

US20080280804A1|2008-11-13|

---

CN1232625C|2005-12-21|

---

WO2002046348A1|2002-06-13|

---

EP1340805A4|2004-05-12|

---

JP3481615B2|2003-12-22|

---

CA2430374A1|2002-06-13|

引用文献:

---

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

---

法律状态:
2000-12-05|Priority to JP2000370238

---

2000-12-05|Priority to JPJP-P-2000-00370238

---

2001-04-04|Priority to JPJP-P-2001-00106419

---

2001-04-04|Priority to JP2001106419

---

2001-12-05|Application filed by 미즈 가부시키가이샤

---

2001-12-05|Priority to PCT/JP2001/010642

---

2003-08-27|Publication of KR20030070056A

---

2005-12-01|Application granted

---

2005-12-01|Publication of KR100533123B1

优先权:

---

申请号 | 申请日 | 专利标题

---

JP2000370238|2000-12-05|

---

JPJP-P-2000-00370238|2000-12-05|

---

JPJP-P-2001-00106419|2001-04-04|

---

JP2001106419|2001-04-04|

---

PCT/JP2001/010642|WO2002046348A1|2000-12-05|2001-12-05|Method of laundering clothes and detergent composition therefor|